Biomass Densification for Energy Production


Factsheet - ISSN 1198-712X   -   Copyright Queen's Printer for Ontario
Agdex#: 737/120
Publication Date: 06/2011
Order#: 11-035
Last Reviewed: October 2015
History:
Written by: Steve Clarke - Engineer, Energy and Crop Engineering Specialist/OMAFRA; Fernando Preto - Bioenergy Systems/CanmetENERGY

Table of Contents

  1. Introduction
  2. Bulk Density
  3. Energy Density
  4. Why Densify?
  5. Pre-Treatment of Biomass
  6. Techniques for Biomass Densification
  7. Biomass Densification Cost
  8. Conclusion
  9. Additional Resources
  10. References
  11. Acknowledgements

Introduction

Biomass fuels are a potential source of renewable energy. One of the major barriers to their widespread use is that biomass has a lower energy content than traditional fossils fuels, which means that more fuel is required to get the same amount of energy. When combined – low energy content with low density – the volume of biomass handled increases enormously. Compaction or densification is one way to increase the energy density and overcome handling difficulties. This Factsheet examines the density properties of solid biomass and potential densification technologies.

Bulk Density

Bulk density is defined as the weight per unit volume of a material, expressed in kilograms per cubic metre (kg/m3) or pounds per cubic foot (lb/ft3). Most agricultural residues have low bulk densities, as shown in Figure 1.

A bar chart showing the bulk densities of unprocessed biomass.

Figure 1. Typical bulk densities of unprocessed biomass materials.

For example, the bulk density of loose wheat straw is approximately 18 kg/m3 (1.1 lb/ft3), in comparison to coal at 700 kg/m3 (44 lb/ft3). For this reason, it generally is only economically feasible to transport unprocessed biomass less than approximately 200 km (Preto 2007).

Energy Density

Energy density is a term used to describe the amount of energy stored per unit volume, often expressed in MJ/m3 or BTU/ft3.

Figure 2 is a graphical representation of common volume ratios for unprocessed material, with the cubes representing the volume of material required for equal energy, 16:4:1 for straw to wood to coal.

Why Densify?

The low density of biomass materials poses a challenge for the handling, transportation, storage and combustion processes. These problems may be addressed through densification, a process that produces either liquid or solid fuel with denser and more uniform properties than the raw biomass.

A drawing of three boxes, the largest with the word straw written across the centre, followed by a smaller middle box with the word wood written across the centre and a small box with the word coal written across the centre.  The diagram shows the equivalent energy content by volume of unprocessed materials.

Figure 2. Equivalent energy content by volume of unprocessed materials. Source: Preto (2007).

The main advantages of biomass densification for combustion are:

  • simplified mechanical handling and feeding
  • uniform combustion in boilers
  • reduced dust production
  • reduced possibility of spontaneous combustion in storage
  • simplified storage and handling infrastructure, lowering capital requirements at the combustion plant
  • reduced cost of transportation due to increased energy density

The major disadvantage to biomass densification technologies is the high cost associated with some of the densification processes.

Pre-Treatment of Biomass

Prior to biomass densification, pre-treatments may be required to optimize the energy content and bulk density of the product.

Pre-treatment can include:

  • chop length/grinding
  • drying to required moisture content
  • application of a binding agent
  • steaming
  • torrefaction

Chop Length/Grinding

Each densification process requires specific chop length and/or grinding to achieve:

  • lower energy use in the densification process
  • denser products
  • a decrease in breakage of the outcome product (Dobie 1959)

Drying

Low moisture results in improved density and durability of the fuel (Shaw and Tabil 2007). For most biomass densification processes, the optimum moisture content is in the range of 8%–20% (wet basis) (Kaliyan and Morey 2009). Most compaction techniques require a small amount of moisture to "soften" the biomass for compaction. Above the optimum moisture level, the strength and durability of the densified biomass are decreased.

Addition of a Binding Agent

The density and durability of densified biomass are influenced by the natural binding agents of the material. The binding capacity increases with a higher protein and starch content (Tabil et al. 1997). Corn stalks have high binding properties, while warm-season grasses, which are low in protein and starch content, have lower binding properties (Kaliyan and Morey 2006). Binding agents may be added to the material to increase binding properties. Commonly used binders include vegetable oil, clay, starch, cooking oil or wax.

Steaming

The addition of steam prior to densification can aid in the release and activation of natural binders present in the biomass.

Torrefaction

Torrefaction is a version of pyrolysis processes that comprise the heating of biomass in the absence of oxygen and air. Torrefaction is a pre-treatment process used to improve the properties of pellets. It can also be used as a stand-alone technique to improve the properties of biomass. Torrefaction is a mild version of slow pyrolysis in which the goal is to dry, embrittle and waterproof the biomass. This is accomplished by heating the biomass in an inert environment at temperatures of 280°C–320°C.

Techniques for Biomass Densification

Biomass is densified via two main processes: mechanical densification and pyrolysis. Mechanical densification involves applying pressure to mechanically densify the material. Pyrolysis involves heating the biomass in the absence of oxygen. In general, lower temperatures at longer processing times (i.e., slow pyrolysis) favour solid (charcoal) production. Medium temperatures (400°C–500°C) at very short times (1–2 seconds), known as fast pyrolysis, favour liquid or bio-oil production.

The method of densification depends on the type of residues and the local situation. Table 1 outlines the various technologies used to increase the biomass energy density and/or mould the fuel into a homogeneous size and shape.

Conversion
From to Multiply by
mm inch 0.0394
inch ft 0.0833
kg/m3 lb/ft3 0.0624
MJ/kg BTU/lb 430

Table 1. Densification technologies

Mechanical densification

Bales are a traditional method of densification commonly used to harvest crops. A bale is formed using farm machinery (called a baler) that compresses the chop. Bales can be square, rectangular or round, depending on the type of baler used. The dimensions of round bales range from 1.2 m x 1.5 m (4 ft x 5 ft) to 1.5 m x 1.5 m (5 ft x 5 ft). Large rectangular bales typically measure 0.9 m x 0.9 m x 1.8 m (3 ft x 3 ft x 6 ft) in length. Round bales are less expensive to produce, however, large square bales are usually denser and easier to handle and transport.

A photo showing two round bales of hay in a field.


Pellets are very high in density. They are easier to handle than other densified biomass products, since infrastructure for grain handling is used for pellets. Pellets are formed by an extrusion process, using a piston press, where finely ground biomass material is forced through round or square cross-sectional dies and cut to a desired length. The standard shape of a biomass pellet is a cylinder, having a length smaller than 38 mm (1.5 in.) and a diameter around 7 mm (0.3 in.). Although uniform in shape, pellets are easily broken during handling. Different grades of pellets vary in energy and ash content. Photo courtesy of CanmetENERGY.

A photo showing a small pile of pellets.


Cubes are larger pellets, usually square in shape. Cubes are less dense than pellets. Cube sizes range from 13–38 mm (0.5–1.5 in.) in cross section, with a length ranging 25–102 mm (1–4 in.). The process involves compressing chopped biomass with a heavy press wheel, followed by forcing the biomass through dies to produce cubes. Photo courtesy of CanmetENERGY.

A photo showing a small pile of square shaped cubes of biomass.


Briquettes are similar to pellets but differ in size. Briquettes have a diameter of 25 mm (1 in.) or greater and are formed when biomass is punched, using a piston press, into a die under high pressure. Alternatively, a process referred to as screw extrusion can be used. In screw extrusion, the biomass is extruded by a screw through a heated die. Biomass densified through screw extrusion has higher storability and energy density properties compared to biomass produced by piston press. Photo courtesy of Wayne Winkler.

A photo showing a briquette of biomass.


Pucks are similar in appearance to a hockey puck, with a 75 mm (3 in.) diameter. They are produced using a briquetter and are resilient to moisture. Pucks have a similar density as pellets, with the advantage that they require lower production costs compared to pelletization.

A photo showing 4 round biomass pucks stacked on each other.


Wood Chips are used in many operations, from household appliances to large-scale power plants. Woodchips for boilers range in size, 5–50 mm (0.2–2 in.) in length. Woodchips are made with a woodchipper. In terms of fuel, woodchips are comparable in cost to coal. Photo courtesy of CanmetENERGY.

A photo showing wood chips.


Pyrolysis

Torrefaction is carried out by heating biomass in an inert atmosphere at temperatures of 280°C–320°C for a few minutes. The torrefied fuel shows improved grindability properties. Torrefied biomass has hydrophobic properties (repels water), making it resistant to biological attack and moisture, thereby facilitating its storage. The process requires little energy input since some of the volatile gases liberated during heating are combusted, generating 80% of the heat required for torrefaction. Torrefied biomass is densified into pellets or briquettes, further increasing the density of the material and improving its hydrophobic properties. Photo courtesy of CanmetENERGY.

A photo showing a pile of biomass pellets created through torrefaction.


Slow Pyrolysis involves heating biomass to 350°C–500°C in the absence of oxygen and air for extended periods of time (typically 0.5–2 hours). The principal product is a solid (charcoal) that retains 60%–70% of the original energy from the raw biomass. The energy density can be increased, and thus charcoal is a suitable fuel for commercial uses similar to torrified biomass, residential use, i.e., barbecues, and as a potential soil improvement additive known as bio-char. Photo courtesy of CanmetENERGY.

A photo showing charcoal that has been created using slow pyrolysis.


Fast Pyrolysis involves processing biomass at temperatures of up to 450°C–500°C for 1–2 seconds. The process yields up to 75% bio-oil and 10%–15% charcoal. Bio-oil is a higher-energy density fuel, and its handling properties are simplified, as the fuel is a liquid that is pumped and stored in tanks. Precautions are necessary, as bio-oils are very acidic, have a pungent odour and are prone to separation/settling. Substitute bio-oil for fossil fuel, heavy and middle oils. Research is under way to explore conversion to lighter oils such as diesel and gasoline. Photo courtesy of CanmetENERGY.

A photo showing a lab technician pouring a bio-oil from one beaker to another.


Through various densification technologies, raw biomass is compressed to densities in the order of 7–10 times its original bulk density (Demirbas et al. 2009). The bulk densities for selected pre-processing technologies are displayed in Table 2, as well as in Figure 3.

Table 2. Density of biomass for selected densification technologies
Form of biomass Shape and size characteristics Density(lb/ft3) Density(kg/m3) Energy density (GJ/m3)
Traditional method
Baled biomass3 Large round, Soft core 1.2 x 1.2, 1.2 x 1.5, 1.5 x 1.2, 1.8 x 1.5 m (4 x 4, 4 x 5, 5 x 4, 6 x 5 ft) diameter x width 10–12 160–190 2.8–3.4
Large round, Hard core 1.2 x 1.2, 1.2 x 1.5, 1.5 x 1.2, 1.8 x 1.5 m (4 x 4, 4 x 5, 5 x 4, 6 x 5 ft) diameter x width 12–15 190–240 3.4–4.5
Large/Mid-size square 0.6 x 0.9 x 2.4 m (2 x 3 x 8 ft) 0.9 x 1.2 x 2.4 m (3 x 4 x 8 ft) 13–16 210–255 3.7–4.7
Non-traditional method
Ground biomass1 (i.e., hammermill) 1.5 mm (0.06 in.) pack fill with tapping 13 200 3.6
Briquettes1 32 mm (1.3 in.) diameter x 25 mm (1 in.) thick 22 350 6.4
Cubes1 33 mm (1.3 in.) x 33 mm (1.3 in.) cross section 25 400 7.3
Pucks4 75 mm (3 in.) diameter x 12 mm (0.5 in.) thick 30–40 480–640 8.6–12.0
Pellets1 6.24 mm (0.2 in.) diameter 35–45 550–700 9.8–14.0
Torrefied pellets2 6.24 mm (0.2 in.) diameter 50 800 15.0
Bio-oil2 liquid 75 1,200 20

Note: Loose biomass has a density of 3.5–5 lb/ft3 or 60–80 kg/m3

Source: 1Sokhansanj et al. (2006); 2Kiel (2007), 3Clarke (1995), 4Winkler

Biomass Densification Cost

Pyrolyzed materials are the most expensive to densify, with cubes, pucks, briquettes and woodchips being less expensive.

Factors affecting the cost of densification technologies include (Mani 2006):

  • size of densification plant (tonnes/year)
  • operating time (hours/day)
  • equipment cost
  • personnel cost
  • raw material costs

Densification technologies result in higher energy inputs and increased costs. A portion of the cost is recuperated by the lower handling, storage and transportation costs, and better operability of the boiler and combustion process. Some densification technologies mentioned are commercially available, while others are emerging.

A bar chart showing the bulk densities of biomass based on various densification technologies.

Figure 3. Resulting bulk densities of biomass for selected densification technologies.

Conclusion

The low-energy density of biomass by volume, in comparison with fossil fuels, results in higher handling, storage and transportation costs. Consequently, biomass is most economically feasible when used close to the source. The cost of biomass transportation is reduced through densification technologies. Densification technologies produce a homogeneous product with a higher energy density than that of the original raw material, at the expense of new capital and operating costs.

Additional Resources

References

  • Blasi, D.A., Reed, C.J., Kuhl, G.L., Trigo-Stockli, D.M., Drouillard, J.S., Behnke, K.C., and Fairchild, F.J. (1998). Wheat middlings: composition, feeding value and storage guidelines. Kansas State University: Agricultural Experiment Station and Cooperative Extension Service. p. 21.
  • Demirbas, K., Sahin-Demirba, K.A. (2009). Compacting of biomass for energy densification. Energy Sources, Part A: Recovery, Utilization and Environmental Effects. 1556–7230, 31(12), 1063–1068.
  • Dobie, J.B. (1959). Engineering appraisal of hay pelleting. Agricultural Engineering, 40(2), 72–76.
  • Kaliyan, N., Morey, V. (2006). Densification characteristics of corn stover and switchgrass. ASABE Paper No. 066174. St. Joseph, Mich.: ASABE.
  • Kaliyan, N., Morey, R.V. (2009). Factors affecting strength and durability of densified biomass products. Biomass Bioenergy 33 (3), 337–359.
  • Kiel, J. (2007). Torrefaction for biomass upgrading into commodity fuels. Presentation to IEA Bioenergy Task 32 Workshop "Fuel storage, handling and preparation and system analysis for biomass combustion technologies." Berlin Germany, 7 May 2007.
  • Mani, S., Sokhansanj, S., Bi, X., and Turhollow, A. (2006). Economics of producing fuel pellets from biomass. Applied Engineering in Agriculture, 22(3), 421–26.
  • Murphy, W.J. (2006). Tables for weights and measurement: Crops. Retrieved from: University of Missouri Extension.
  • Preto, F. (2007). Strategies and techniques for combustion of agricultural biomass fuels. Growing the Margins Energy Conference.
  • Reisinger, K., Haslinger, C., Herger, M., and Hofbauer, H. (2006). BIOBIB – A database for biofuels. University of Technology Vienna: Institute of Chemical Engineering, Fuel and Environmental Technology, Austria.
  • Shaw, M. and Tabil, L. (2006). Mechanical properties of selected biomass grinds. ASABE Annual International Meeting. Portland Oregon. July 9–12, 2006. Paper No. 066175. p.12.
  • Shaw, M., and Tabil, L. (2007). Compression and relaxation characteristics of selected biomass grinds. ASABE Paper No. 076183. St. Joseph, Mich.: ASABE.
  • Sokhansanj, S., and Fenton, J. (2006). Cost benefit of biomass supply and pre-prossessing. Biocap Research Integration Program Synthesis Paper.
  • Tabil, L.G., Sokhansani, S., and Tyler, R.T. (1997). Performance of different binders during alfalfa pelleting. Canadian Agricultural Engineering, 39(1), 17–23.
  • Winkler, W. (2010). Briquetting Systems. New York.

Acknowledgements

A special thanks is extended to Chantal Quesnel for all of her hard work in helping create this Factsheet, Benjamin Bronson for his contributions and conscientious review and Shalin Khosla, Greenhouse Specialist, OMAFRA, for his considerable assistance in evaluating alternate technologies.


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